Preheat the oven to 375 degrees and generously grease a bundt pan with non-stick cooking spray.
Add the butter, water, oil, and cocoa to a saucepan and bring to a boil. Then, remove from heat.
In a mixing bowl, add the flour, sugar, salt, and baking soda. Stir to combine.
Carefully pour the chocolate mixture into the dry ingredients and mix well.
Then, stir in the pumpkin puree, eggs, pumpkin spice, and vanilla extract.
Pour the batter into the prepared bundt pan and bake for 50-55 minutes, or until completely cooked through.
Allow the cake to cool completely before removing it from the bundt pan.